Recent progress regarding the bioactivities, biosynthesis and …
网页2014年1月27日 · Among natural macrolides, resorcinylic acid lactones (RALs) and dihydroxyphenylacetic acid lactones (DALs), which are characterized by possessing a macrolide core structure fused to a resorcinol...
Resorcinol: A potentially bio-based building block for the …
网页2015年12月1日 · Potentially bio-based aromatic polyesters with a kinked structure based on resorcinol have been successfully prepared. The process involves an optimized reaction between resorcinol and ethylene carbonate: the diol thus obtained was polymerized with several aliphatic and aromatic dicarboxylic acids.
网页Resorcinolic macrolides, an important subgroup, possess interesting structures and exhibit a wide variety of bioactivities, such as anti-tumor, anti-bacteria, and anti-malaria activities,...
Structural insights into biosynthesis of resorcinolic lipids by a …
网页2008年6月1日 · Here, we report the structural and mutational investigations of a novel type III PKS protein from Neurospora crassa involved in the biosynthesis of resorcinolic metabolites by utilizing long chain fatty acyl-CoAs. The structure revealed a long hydrophobic tunnel responsible for its fatty acyl chain length specificity resembling that of …
Genome mining of multi-substituted alkylresorcinols from a hybrid ...
网页2024年7月1日 · Fungal alkylresorcinols are commonly synthesized by the hybridization of highly reducing polyketide synthase (hrPKS) with non-reducing polyketide synthase (nrPKS). In this study, a new assembly machinery using hrPKS FscA and type III PKS FscB was revealed, and three iterative enzymatic catalysts for 14e− oxidation, di …
Alkylresorcinol biosynthesis in plants: new insights from an …
网页Specialized type III polyketide synthases (referred to as 'alkylresorcinol synthases'), which catalyze the formation of 5-alkylresorcinols using fatty acyl-CoA starter units and malonyl-CoA extender units, have been characterized from several microbial species, however until very recently little has been known concerning their plant counterparts.
Biosynthesis of lipid resorcinols and benzoquinones in isolated ...
网页2007年10月10日 · It had been postulated that the biosynthesis of sorghum lipid resorcinols and benzoquinones was compartmentalized in root hairs. Our research demonstrates that the entire metabolic machinery necessary for the biosynthesis for these molecules is indeed present in these specialized cells.
Biosynthesis of lipid resorcinols and benzoquinones in isolated ...
网页The activity of the key enzymes involved in the biosynthesis of lipid resorcinols and benzoquinones was measured directly in isolated root hair preparations obtained from 6-d-old roots. The purified root hair preparation readily converted long-chain acyl-CoA starter units to their corresponding lipid resorcinols and decanoyl-CoA was the best ...
Biosynthesis of lipid resorcinols and benzoquinones in isolated ...
网页2007年2月1日 · The activity of the key enzymes involved in the biosynthesis of lipid resorcinols and benzoquinones was measured directly in isolated root hair preparations obtained from 6-d-old roots.
Biosynthesis and function of bacterial dialkylresorcinol compounds ...
网页2015年8月14日 · The clustering and distribution of the DAR biosynthesis gene clusters (BGC), that has been identified in more than 100 genomes from taxonomically distinct bacteria, is discussed regarding the structures of the …
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