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2,3-σ迁移(2,3-sigmatropic rearrangement),或称2,3-σ重排,是σ迁移反应的一种,可以分为两种类型:烯丙基亚砜、氧化胺、亚硒砜的重排是中性的;而烯丙基醚的碳负离子重排则涉及到阴离子。 [1] 该重排的一般机理为: 原子 Y 可以是硫、硒或氮。如果 Y 是氮,且 ...
Multiple Triplet Metal-Centered Jahn-Teller Isomers Determine Temperature-Dependent Luminescence Lifetimes in [Ru(bpy)3 ]2.
The University of Waterloo acknowledges that much of our work takes place on the traditional territory of the Neutral, Anishinaabeg, and Haudenosaunee peoples. Our main campus is situated on the ...
Development of 18F-Labeled hydrophilic trans-cyclooctene as a bioorthogonal tool for PET probe construction.