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18 天
福州大学,ACS Catal.!
电化学硝酸盐还原反应(NO3RR)采用硝酸盐(NO3−)作为原料,具有较高的溶解度和较低的N=O解离能(204 kJ mol-1)。这有效地降低了在温和条件下NO3−通过电化学途径转化为NH3的传质阻力和反应障碍。NO3RR涉及一个复杂的八电子耦合九质子转移过程,这可能导致多个中间体 ...
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